Samukai appeared in The Great Invasion!
Despite fighting on his own, he seeks for Yveltal to assist him. In the end of the episode, he was badly damaged by a combination attacks from all the Pokémon commanded by the trainers, then he was killed by Flurr by crushing him by his foot.
Under Samukai's control, Its known moves are Dark Pulse, Oblivion Wing and Dragon Rush, and its ability is Dark Aura.
Under Samukai's control, Its known moves are Shadow Force, Shadow Thunder, Confuse Ray, and its ability is Levitate.